Guidelines for controlling flowaccelerated corrosion in fossil and combined cycle plants 1008082 final report, march 2005 disclaimer of warranties and limitation of liabilities this document was prepared by the organizations named below as an account of work sponsored or cosponsored by the electric power research institute, inc. Leiro corrosion of aluminum and aluminum alloys in nitric acid elmarmanfred horn and helmut w. Several types of corrosion occur in a variety of situations in the nuclear power plants. In this mechanism, the metal undergoes corrosion in order to regain the oxide. Test duration may be selected to achieve any desired level of corrosion exposure and provides a frame of reference to determine relative.
Introduction the flow accelerated corrosion fac, liquid droplet impingement ldi corrosion, and cavitation erosion ce corresponding author. By definition, the rate of fac depends on the flow velocity. Flowaccelerated corrosion fac, also known as flowassisted corrosion, is a corrosion mechanism in which a normally protective oxide layer on a metal surface dissolves in a fast flowing water. Some common mechanisms leading to failures in heat recovery steam generators by dave christophersen, cwt, and dr. Caused by the dissolution of oxide layer on the inside surface of piping in flowing water or wetsteam. Some common mechanisms leading to failures in heat. Corrosionpedia what is flowaccelerated corrosion fac. The pipe wall thinning due to this degradation mechanism in carbon steel piping is not due to the mechanical effect only, however.
Flow accelerated corrosion in horizontal deaerators summary. Flowaccelerated corrosion fac is a type of corrosion where a normally protective film oxide present on surfaces like metal undergoes dissolution in fastflowing liquid, such as water. Some of these types are common such as rusting of steel when located in moist environment, and the other type of corrosion such as flow accelerated corrosion required special treatment due to their impact on the plant safety and reliability. Pdf flow accelerated corrosion fac is distinct from erosion and is primarily an electrochemical corrosion process aided by chemical.
The international association for the properties of water. Alternate wet and dry cycles in the life of a system can create very serious corrosion problems mostly due to the formation of partially dry corrosion products that can further the accumulation of corrosive agents by absorption of moisture and the creation of under deposit corrosion. Zone turbulent flowrates of metal mass losses are determined by a transfer of active components to the metal surface. Control of flowaccelerated corrosion in steam generators. This, the first topical report addresses flow accelerated corrosion fac of carbon steel and low alloy steel piping. Flow accelerated corrosion fac inspection using pocket ut. In 1998 a method called accelerated corrosion test involving alternate exposure for hostile gases, neutral salt spray and drying, sp method 2499, was developed.
Susceptible components include carbon steel and low alloy steel piping, tubing and vessels. R, flowaccelerated corrosion in fossil and combined cyclehrsg plants, ppchem journal 2008,pg 6889 chakraborty p. When a particular plant has the cycle chemistry optimized, the general corrosion and flowaccelerated corrosion fac in the feedwater, condensate, and low temperature circuits where attack can be the highest should be minimal. Corrosion of steel reinforcement in concrete is always in the news, and it starts off as pitting, caused by chloride ionsso it is feasible that pitting is the most costly form of corrosion.
Accelerated test for determining microbiologicalinfluenced corrosion resistance of aluminum alloysb. Flow accelerated corrosion fac, wall thinning rate tr, orifice, gasliquid bubble flow, turbulent kinetic energy, pressure fluctuation p, estimation of p or tr, suppression of p or tr 1. The pipe wall thinning due to this degradation mechanism in carbon steel piping is not due to the mechanical effect only, however, the wall thinning is mainly due to dissolution of normally protective magnetite film that normally forms on the internal pipe wall surface. Predictive modelling of flowaccelerated corrosion vtt. Significant metal thickness is sometimes lost from the pressure shell as a result of this effect. Bse to organise th middle east corrosion conference in bahrain. Flow accelerated corrosion f ac is distinct from erosion and is primaril y an electrochemical corrosion process aided by chemical dissolution and mass t ransfer. Present research deals with comparing the protection offered by the magnetite fe3o4 versus maghemite. Scientists have proposed a new cyclic corrosion test cct for evaluating corrosion resistance of anticorrosion coatings. Flow accelerated corrosion facalso called erosion corrosion ecand cavitation are significant and costly damage mechanisms common to all types of utility and industrial steam and hot water cycles.
There exists two types of accelerated corrosion testing. Control of flowaccelerated corrosion in steam generators by brad buecker, process specialist kiewit power engineers preface in 2012, the author gave a paper on flowaccelerated corrosion at the 73rd annual international water conference. Flow accelerated corrosion fac of carbon steel and low alloy steel. Fac involves wall thinning of carbon and lowalloy steel highenergy piping due to turbulent and fast flowing water or wet steam that wears away the oxide layer protective film and leads to. Accelerated corrosion testing services offered at micom laboratories. The reasons for a maxima being observed in fac rates at 150170. Flow accelerated corrosion experience at comanche peak. Pdf predicting and preventing flow accelerated corrosion. Flowaccelerated corrosion fac, also denoted as erosioncorrosion. Combined life cycle heat recovery steam generators hrsg play a vital role in energy efficiency, reducing green house effect. Flow accelerated corrosion fac is a very serious problem in power generation facilities. Complete document available on olis in its original format.
Flow accelerated corrosion fac damage in the high pressure evaporator circuit with potential lengthy outage for replacement. Flowaccelerated corrosion is wall thinning of steel piping due to turbulent and fast flowing water or wet steam that wears away the protective film oxide layer and leads to continued corrosion of the underlying metal. An accelerated corrosion test is a cyclic climate test for determination of the corrosion resistance of various types of coatings. Several are described more in terms of practical corrosion concepts rather than as formal definitions. Flow accelerated corrosion fac is a major concern in the power industry as it causes thinning of the pipes by the dissolution of the passive oxide layer formed on the pipe surface. Flowaccelerated corrosion fac is metal loss that occurs in carbon steel equipment when the normally. This paper addresses the principal environmental conditions that have been linked to flow accelerated corrosion and it. Apparently, the phenomenon is more widespread than is realized and has been misdiagnosed as simple erosion. The corrosion rate decreases as the cr content increases. Piping failures caused by flow accelerated corrosion fac have occurred at both nuclear and fossilfuel power plants, several with fatal consequences.
Accelerated corrosion tests are cyclic climate tests that assess metal surfaces ability to resist corrosion. The division was established in 1942, but corrosion has. Methods are developed for mimicking an actual corrosion process in nature. Fac is a chemical effect that is primarily influenced by. Flow accelerated corrosion fac, also denoted as erosion corrosion, of carbon or lowalloyed steel piping occurs when the rate of dissolution of the protective oxide film that forms on the internal piping surface into a stream of flowing water or wet steam is enhanced, leading to an increased wall thinning rate 14. More than 40% of heat recovery steam generator hrsg tube failures are due to flow accelerated corrosion fac. Corrosion rate increases as the flow rate increases. For reference purposes, fac is a type of erosioncorrosion that may affect a number of systems in modern power plants. Bakirov 8 processes of the flowaccelerated corrosion zone laminar flowvery low rates of corrosion.
Facilities instructions, standards, and techniques volume. Flow accelerated corrosion fac is distinct from erosion and is primarily an electrochemical corrosion process aided by chemical dissolution and mass transfer. The most common accelerated corrosion test is astm b117 also called salt spray test. The underlying metal corrodes to recreate the oxide, and thus the metal loss continues. In an accelerated corrosion test, corrosion, degradation or failure of materials and products are induced without change in corrosion mechanisms in a shorter time period than under normal conditions. Flow accelerated corrosion fac causes wall thinning metal thickness loss of carbon steel piping, tubing and vessels exposed to flowing water or wet steam. Corrosion phenomenon causing the impairment of the metal function, of the environment or of the technical system of which they form a part.
During the routine inspection of horizontal deaerators, advanced flowaccelerated corrosion is frequently discovered on the bottom of the heater vessel shell. Download fulltext pdf download fulltext pdf predicting and preventing flow accelerated corrosion in nuclear power plant article pdf available october 2014 with 1,394 reads. Pipe wall thickness progressively reduceto point of rupture. Flow accelerated corrosion in nuclear power plants intechopen. In addition to the astm b117 test, we can also conduct the following. Minimizing corrosion risks of low load operation uniper. Flow accelerated corrosion has recently attracted attention in association with heat recovery steam generators. Accelerated corrosion testing the purpose of an accelerated corrosion test, such as the salt spray test, is to duplicate, in the laboratory, the corrosion performance of a product in the field. Determinationcontrol of multiphase flows and flow accelerated corrosion, ndt in nonmetallic materials and proper procurement methodology of sour service materials. Increases in flow rates associated with larger units and improved oxygen control have provided. Flowaccelerated corrosion facalso called erosioncorrosion ecand cavitation are significant and costly damage mechanisms common to all types of utility and industrial steam and hot water cycles.
Accelerated low water corrosion alwc is a high profile corrosion problem that can occur on steel maritime structures. Development of accelerated corrosion tests involving. The forms of erosion including single and dual phase fac and liquid droplet impingement are discussed and differentiated. Flow accelerated corrosion fac refers to the combined actions involving the removal of magnetite fe 3 o 4 layer by fluid flow and the subsequent increased corrosion of the exposed metal, leading to wall thinning metal loss to the extent of perforation. Accelerated corrosion testing services micom laboratories.
L, flow accelerated corrosion failures in refineries hydrocarbon asia journal, julysept 2012, pg 4046. During the routine inspection of horizontal deaerators, advanced flow accelerated corrosion is frequently discovered on the bottom of the heater vessel shell. Flow accelerated corrosion fac fac1 chemistry affects are strong on flow accelerated corrosion fac. This allows scientists and engineers the opportunity to advance the development of new products in a quick manner. Corrosion attack is accelerated, where the oxygen concentration is least. Flow accelerated corrosion how is flow accelerated. Standard guide for accelerated corrosion testing for. Temperature also has a pronounced effect on fac wear rate. The corrosion rate increases when do becomes less than a few ppb. Corrosion damage characterized by the complete loss of operational capability of the technical system. Flow accelerated corrosion failures in gas to liquids. Corrosion, though commonly associated with metals, can affect any. Erosion corrosion page 10 1 erosion corrosion flowassisted corrosion an increase in corrosion brought about by a high relative velocity between the corrosive environment and the surface. According to the ice maritime board, repair costs resulting from alwc on.
Corrosion mechanisms such as general and crevice corrosion may be evaluated with this method. Douglas bain originally presented at the national association of corrosion engineers convention 2003 a bstract failures due to flow accelerated corrosion have occurred in. Flowaccelerated corrosion in pipe wall downstream of. Pitting corrosion of metals electrochemical society. Pdf s the phenomenon of flow accelerated corrosion fac, also known as erosioncorrosion ec hearafter referred to as fac ec is often observed. Fourier transform infrared spectroscopy ftir is used. Flow accelerated corrosion several steps to prevent. Flow accelerated corrosion in nuclear power plants.
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